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S. Yu. Lanskaya, A. V. Bashilov, Yu. A. Zolotov

Investigation of Kinetics of Ruthenium(IV) Complexation with Nitroso P Salt under Microwave Irradiation. Comparison with Classical Heating

Abstract

The kinetics of complexation in the system ruthenium(IV) – Nitroso R Salt under classical heating (60–98°C) and under microwave irradiation (60–160°C) was studied. Rate constants, activation energies, and ratio of components were evaluated. It was pointed that the pre-exponential coefficient in Arrhenius’s equation is influenced by nonthermal effect of microwave irradiation.
Moscow University Chemistry Bulletin.
2006, Vol. 47, No. 3, P. 182
   

Copyright (C) Chemistry Dept., Moscow State University, 2002
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