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D. Yu. Kultin, A. V. Ivanov, O. K. Lebedeva, L. M. Kustov
Electrochemical syntheses of polyphenilethylens
in room-temperature ionic liquids
Abstract
Electrochemical oxidation of benzene in
room-temperature ionic liquids on the base of complex N -
butylpyridiniumchloride and AlCl3 ([PyBuCl]Al2Cl6)
under controlling potential on platinum and glassycarbon composite (GlC)
electrodes electrodes was studied. Linear polymers (degree of polymerization
was 8 – 120) were obtained as products. It was shown that the degree
of polymerization is increasing in according with electrodes potential. The
characterization of reaction products was performed using FTIR spectroscopy.
Copyright (C) Chemistry Dept., Moscow State University, 2002
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