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Химический факультет МГУ

Кафедра органической химии

Лаборатория Элементоорганических Соединений (ЭОС)

Заведующий лабораторией - академик РАН, профессор Белецкая Ирина Петровна,
Телефон (495) 939-36-18
E-mail: beletska@org.chem.msu.ru


Основные направления научных исследований.

Тематика исследований:

  • металлокомплексный и органический катализ
  • химия макроциклических соединений и создание хемосенсоров на их основе
  • химия порфиринов и стероидов
  • металлцентрированные нуклеофилы

Cотрудники лаборатории ЭОС:

  • к. 526 - д.х.н. профессор Лукашев Н.В., с.н.с. к.х.н. Латышев Г.В., м.н.с. к.х.н. Казанцев А.В., аспирант Котовщиков Ю., аспирант Ерзунов Д., дипломник Навасардян М.
  • к. 507 и к. 511 - д.х.н. в.н.с. Аверин А.Д., к.х.н. доцент Вейц Ю.А., н.с. к.х.н. Анохин М.В., м.н.с. к.х.н. Михалицына Е.А., асп. Якушев А., асп. Григорова О., асп. Десяткин В., асп. Черниченко Н., асп. Абель А., асп. Мурашкина А., дипл. Панченко С., дипл. Шевчук В., дипл. Гурьев А.
  • к. 522 - к.х.н. доцент Гулюкина Н.С., м.н.с. к.х.н. Макухин Н., асп. Шергольд И., асп. Волкова М., асп. Митрофанов А., дипломник Шинкарев Е.
  • к. 516 - д.х.н. в.н.с. Кашин А.Н.
  • к. 509 - н.с. к.х.н. Ганина О.Г., м.н.с. Бондаренко Г.Н.
  • к. 420 - с.н.с. к.х.н. Тарасенко Е.А., м.н.с. к.х.н. Патрикеева-Роча Л.С., с.н.с. к.х.н. Титанюк И.Д.
  • к. 421 - н.с. к.х.н. Тростянская И.Г., н.с. к.х.н. Савинова Т.С.
  • к. 217 - с.н.с. к.х.н. Сазонов П.К.
  • к. 215 - доцент к.х.н. Чепраков А.В., асп. Дубровский А., асп. Андрианов Д.
  • к. 213 - н.с. к.х.н. Давыдов Д.В.

Избранные публикации сотрудников лаборатории за 2009-2014 гг:

  1. Thota, B.N.S., A.J. Savyasachi, N. Lukashev, I. Beletskaya, and U. Maitra, Tripodal bile acid architectures based on a triarylphosphine oxide core obtained by copper-catalysed [1,3]-dipolar cycloaddition: Synthesis and preliminary aggregation studies. European Journal of Organic Chemistry, 2014.
  2. Titanyuk, I.D. and I.P. Beletskaya, Palladium-catalyzed hydroarylation of diazoacetic ester. Synlett, 2013. 24(3): p. 355-358.
  3. lukashev
  4. Sazonov, P.K., D.S. Ptushkin, V.N. Khrustalev, N.G. Kolotyrkina, and I.P. Beletskaya, Radical-chain oxidative addition mechanism for the reaction of an [Re(CO 5-anion with a-bromostilbene. Dalton Transactions, 2013. 42(12): p. 4223-4232.
  5. Sazonov, P.K., Y.F. Oprunenko, and I.P. Beletskaya, Predicting the direction of nucleophilic attack in vinyl halides: Halogenophilic versus carbophilic reactivity of metal carbonyl anions. Journal of Physical Organic Chemistry, 2013. 26(2): p. 151-161.
  6. Kotovshchikov, Y.N., G.V. Latyshev, N.V. Lukashev, and I.P. Beletskaya, An efficient approach to azolyl-substituted steroids through copper-catalyzed Ullmann C-N coupling. European Journal of Organic Chemistry, 2013(34): p. 7823-7832.
  7. Abel, A.S., A.D. Averin, O.A. Maloshitskaya, E.N. Savelyev, B.S. Orlinson, I.A. Novakov, and I.P. Beletskaya, Palladium-catalyzed amination of dichloroquinolines with adamantane-containing amines. Molecules, 2013. 18(2): p. 2096-2109.
  8. Trostyanskaya, I.G. and I.P. Beletskaya, Regio- and stereoselective copper-catalyzed addition of aromatic and aliphatic thiols to terminal and internal nonactivated alkynes. Synlett, 2012(4): p. 535-540.
  9. Ranyuk, E.R., M.A. Filatov, A.D. Averin, A.V. Cheprakov, and I.P. Beletskaya, The synthesis of highly basic -extended porphyrins by palladium-catalyzed amination. Synthesis, 2012. 44(3): p. 393-398.
  10. gulukina

  11. Mikhalitsyna, E.A., V.S. Tyurin, I.A. Zamylatskov, V.N. Khrustalev, and I.P. Beletskaya, Synthesis, characterization and cation-induced dimerization of new aza-crown ether-appended metalloporphyrins. Dalton Transactions, 2012. 41(25): p. 7624-7636.
  12. Mikhalitsyna, E.A., V.S. Tyurin, S.E. Nefedov, S.A. Syrbu, A.S. Semeikin, O.I. Koifman, and I.P. Beletskaya, High-yielding synthesis of b-octaalkyl-meso-(bromophenyl)-substituted porphyrins and X-ray study of axial complexes of their zinc complexes with THF and 1,4-dioxane. European Journal of Inorganic Chemistry, 2012(36): p. 5979-5990.
  13. Kobelev, S.M., A.D. Averin, O.A. Maloshitskaya, F. Denat, R. Guilard, and I.P. Beletskaya, Planar-chiral macrobicycles comprising cyclam moiety. Macroheterocycles, 2012. 5(4-5): p. 389-395.
  14. Kobelev, S.M., A.D. Averin, A.K. Buryak, F. Denat, R. Guilard, and I.P. Beletskaya, Pd-catalyzed amination in the synthesis of cyclen-based macrotricycles. Tetrahedron Letters, 2012. 53(2): p. 210-213.
  15. Goulioukina, N.S., I.A. Shergold, G.N. Bondarenko, M.M. Ilyin, V.A. Davankov, and I.P. Beletskaya, Palladium-catalyzed asymmetric hydrogenation of N-hydroxya-imino phosphonates using bronsted acid as activator: The first catalytic enantioselective approach to chiral N-hydroxy-aamino phosphonates. Advanced Synthesis and Catalysis, 2012. 354(14-15): p. 2727-2733.
  16. Colacino, E., J. Martinez, F. Lamaty, L.S. Patrikeeva, L.L. Khemchyan, V.P. Ananikov, and I.P. Beletskaya, PEG as an alternative reaction medium in metal-mediated transformations. Coordination Chemistry Reviews, 2012. 256(23-24): p. 2893-2920.
  17. Beletskaya, I.P. and A.V. Cheprakov, The complementary competitors: Palladium and copper in C-N cross-coupling reactions. Organometallics, 2012. 31(22): p. 7753-7808.
  18. Tarasenko, E.A., V.I. Isaeva, I.P. Beletskaya, and L.M. Kustov, Ionic liquid [BMIM]PF6 as a medium for the selective hydrogenation of 1,4-diacetoxybut-2-yne on the Pd-containing catalysts. Russian Chemical Bulletin, 2011. 60(1): p. 179-181.
  19. tarasenko
  20. Sazonov, P.K., Z.D.Dzambaski, M.M. Shtern, R. Markovic, and I.P. Beletskaya, Reactions of transition metal carbonyl anions with 2-(1-bromoalkylidene) thiazolidin-4-ones: Halogenophilic attack or deprotonation. Tetrahedron Letters, 2011. 52(1): p. 29-33.
  21. Sazonov, P.K., G.A. Artamkina, and I.P. Beletskaya, Halogenophilic and classical AdNE mechanisms in nucleophilic vinylic substitution reactions involving the anions of transition metal carbonyls. Theoretical and Experimental Chemistry, 2011. 46(6): p. 350-358.
  22. Synthesis of 3b-acetoxy-17a-hydroperoxy-16a- methylpregn-5-en-20-one and its reduction to 17?-hydroxy derivative. Russian Journal of Organic Chemistry, 2011. 47(1): p. 54-61.
  23. Ranyuk, E., A. Uglov, M. Meyer, A.B. Lemeune, F. Denat, A. Averin, I. Beletskaya, and R. Guilard, Rational design of aminoanthraquinones for colorimetric detection of heavy metal ions in aqueous solution. Dalton Transactions, 2011. 40(40): p. 10491-10502.
  24. Minaeva, L.I., L.S. Patrikeeva, M.M. Kabachnik, I.P. Beletskaya, B.S. Orlinson, and I.A. Novakov, Synthesis of novel aminomethylenebisphosphonates and bisphosphonic acids, containing adamantyl fragment. Heteroatom Chemistry, 2011. 22(1): p. 55-58.
  25. Kobelev, S.M., A.D. Averin, A.K. Buryak, F. Denat, R. Guilard, and I.P. Beletskaya, Synthesis of macrobi-and macrotricyclic compounds comprising pyrimidyl substituted cyclen and cyclam. Heterocycles, 2011. 82(2): p. 1447-1476.
  26. Goulioukina, N.S., N.N. Makukhin, and I.P. Beletskaya, 1,3-Dipolar cycloaddition of diazoalkanes onto dimethyl 1-(formylamino)ethylenephosphonate: A new route to 1-aminocyclopropanephosphonic acids and 3-phosphorylated pyrazoles. Tetrahedron, 2011. 67(49): p. 9535-9540.
  27. anokhin

  28. Anokhin, M.V., A.D. Averin, and I.P. Beletskaya, Copper-catalyzed arylation of oxadiamines and polyamines. European Journal of Organic Chemistry, 2011(31): p. 6240-6253.
  29. Titanyuk, I.D., D.V. Vorob'eva, S.N. Osipov, and I.P. Beletskaya, Synthesis of a-trifluoromethyl-a-hydroxycarboxylate dervatives and their phosphorus-containing analogs with the use of fluorinated diazo compounds. Russian Journal of Organic Chemistry, 2010. 46(5): p. 619-623.
  30. Ranyuk, E.R., A.D. Averin, and I.P. Beletskaya, One-step synthesis of chiral azamacrocycles via palladium-catalyzed enantioselective amination of 1,5-dichloroanthraquinone and 1,5- dichloroanthracene. Advanced Synthesis and Catalysis, 2010. 352(13): p. 2299-2305.
  31. Minaeva, L.I., M.M. Kabachnik, G.V. Ponomarev, J.V. Morozova, and I.P. Beletskaya, Synthesis of novel chlorin e6 derivatives containing organophosphorus groups. Synthesis, 2010(14): p. 2451-2455.
  32. Kobelev, S.M., A.D. Averin, A.K. Buryak, and I.P. Beletskaya, Amination of 4,6- and 2,4-dichloropyrimidines with polyamines. Russian Journal of Organic Chemistry, 2010. 46(8): p. 1231-1242.
  33. Beletskaya, I.P. and O.G. Ganina, Hydroxy-and alkoxycarbonylation of aryl iodides catalyzed by polymer-supported palladium. Reaction Kinetics, Mechanisms and Catalysis, 2010. 99(1): p. 1-4.
  34. Beletskaya, I.P., A.D. Averin, A.G. Bessmertnykh, F. Denat, and R. Guilard, Palladium-catalyzed amination in the synthesis of polyazamacrocycles. Russian Journal of Organic Chemistry, 2010. 46(7): p. 947-967.
  35. averin
  36. Averin, A.D., A.N. Uglov, A.K. Buryak, A.G. Bessmertnykh, R. Guilard, and I.P. Beletskaya, Synthesis of polyazamacrocycles comprising 6,6'-diamino- 2,2'- bipyridine moieties via Pd-catalyzed amination. Heterocycles, 2010. 80(2): p. 957-975.
  37. Averin, A.D., A.N. Uglov, A.K. Buryak, and I.P. Beletskaya, Pd-catalyzed amination of isomeric dibromobiphenyls: possibilities of one-step synthesis of macrocycles. Mendeleev Communications, 2010. 20(1): p. 1-3.
  38. Tsarev, A.A., M.V. Nikulin, A.V. Lygin, A.N. Ryabov, A.Z. Voskoboinikov, and I.P. Beletskaya, A study of palladium-catalyzed arylation of bis(3-bromo-5-methyl-6H- cyclopenta[b]thien-6-yl)(dimethyl)silane. Doklady Chemistry, 2009. 424(2): p. 31-34.
  39. Sazonov, P.K., L.K. Minacheva, A.V. Churakov, V.S. Sergienko, G.A. Artamkina, Y.F. Oprunenko, and I.P. Beletskaya, Lariat ethers with fluoroaryl side-arms: A study of CF...metal cation interaction in the complexes of N-(o-fluoroaryl)azacrown ethers. Dalton Transactions, 2009(5): p. 843-850.
  40. Ranyuk, E., C.M. Douaihy, A. Bessmertnykh, F. Denat, A. Averin, I. Beletskaya, and R. Guilard, Diaminoanthraquinone-linked polyazamacrocycles: Efficient and simple colorimetric sensor for lead ion in aqueous solution. Organic Letters, 2009. 11(4): p. 987-990.
  41. Latyshev, G.V., M.S. Baranov, A.V. Kazantsev, A.D. Averin, N.V. Lukashev, and I.P. Beletskaya, Copper-catalyzed [1,3]-dipolar cycloaddition for the synthesis of macrocycles containing acyclic, aromatic and steroidal moieties. Synthesis, 2009(15): p. 2605-2615.
  42. Kabytaev, K.Z., S.N. Mukhin, I.V. Glukhov, Z.A. Starikova, V.I. Bregadze, and I.P. Beletskaya, Boron - Oxygen bond formation by palladium-catalyzed etheration of 2-iodo-para-carborane. Organometallics, 2009. 28(16): p. 4758-4763.
  43. Kabachnik, M.M., L.I. Minaeva, and I.P. Beletskaya, Synthesis of novel a-aminophosphonates containing adamantyl fragment. Synthesis, 2009(14): p. 2357-2360.
  44. Goulioukina, N.S., G.N. Bondarenko, A.V. Bogdanov, K.N. Gavrilov, and I.P. Beletskaya, Asymmetric hydrogenation of a-keto phosphonates with chiral palladium catalysts. European Journal of Organic Chemistry, 2009(4): p. 510-515.
  45. sazonov

  46. Ganina, O.G., A.Y. Fedorov, and I.P. Beletskaya, Palladium-catalyzed reactions of 4-(Trifluoromethylsulfonyloxy)coumarins with amides and NH-heterocycles. Synthesis, 2009(21): p. 3689-3693.
  47. Beletskaya, I.P. and A.V. Cheprakov, Focus on Catalyst Development and Ligand Design. 2009. p. 51-132.
  48. Averin, A.D., A.N. Uglov, E.R. Ranyuk, N.V. Lukashev, and I.P. Beletskaya, Palladium-catalyzed amination in the synthesis of nitrogen and oxygen heterocycles containing fragments of cholane and quinoline. Russian Journal of Organic Chemistry, 2009. 45(2): p. 273-284.
  49. Averin, A.D., A.N. Uglov, A.K. Buryak, and I.P. Beletskaya, Facile synthesis of new polyazamacrocycles by the Pd-Catalyzed amination of 3,3'-dibromobiphenyl. Macroheterocycles, 2009. 2(3-4): p. 275-280.
  50. Averin, A.D., A.V. Shukhaev, A.K. Buryak, F. Denat, R. Guilard, and I.P. Beletskaya, Synthesis of 1,3-bis(trimethylcyclam) and 1,3-bis(trimethylcyclen) substituted benzenes. Macroheterocycles, 2009. 2(3-4): p. 281-285.
  51. Averin, A.D., E.R. Ranyuk, A.K. Buryak, E.N. Savelyev, B.S. Orlinson, I.A. Novakov, and I.P. Beletskaya, Pd-catalyzed amination in the synthesis of a new family of polyazamacrocycles containing 1,3-disubstituted adamantane moieties. Mendeleev Communications, 2009. 19(3): p. 136-138.




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