Elena N. Golubeva

Senior researcher, PhD in Chemistry

Elena. N. Golubeva was born in 1962, 20 February. Elena. N. Golubeva entered Chemical Department of Lomonosov Moscow State University in 1979, and graduated from it in 1984 after defending the diploma work "Kinetics and mechanism of beta-chlorostyrene chlorination". Since 1982 she works in the chair of chemical kinetics of the Chemistry department of Lomonosov Moscow State University. In 1991 she defended candidate thesis "Kinetics and mechanism of processes in the systems allylhalide - iron (III) chloride - organic solvent" (with Tatiana N. Rostovshchikova as scientific advisor). E. N. Golubeva is the co-author of 32 articles in the scientific journals, 5 certificates of authorship of the USSR and two Russian federation patents. Under her management 6 diploma works and one candidate thesis were defended. E. N. Golubeva is the member of the organization committee of the international conference "Atmosphere, ionosphere, safety" (2008, 2010).

Contacts

Scientific interests

Redox catalysis, radical reactions, the photochemical transformations of metal complexes, quantum chemistry

Selected publications

1. V. V. Smirnov, E. N. Golubeva, O. A. Zagorskaya, S. M. Nevskaya, M. M. Levitskii, and V. Yu. Zufman, Radical-Chain Reactions of CCl4 with Hydrocarbons in the Presence of Silica-Immobilized Copper-Containing Catalysts. Kinetics and Catalysis 2000, V.41, №3, p.399
2. V.V.Smirnov, E.N.Golubeva Quantum-chemical investigation of Cu-containing catalysts for C-Cl bond metathesis, J.Mol.Cat, 2000, V.158, p.487-493
3. E. N. Golubeva, A. I. Kokorin, D. I. Kochubei, V. I. Pergushov, and V. V. Kriventsov, Structure and Composition of the Anionic Chloride Complexes of Copper(II) as the Precursors of Catalysts for C–Cl Bond Metathesis. Kinetics and Catalysis 2002, V. 43, № 3, p. 408
4. V. V. Smirnov, V. M. Zelikman, I. P. Beletskaya, E. N. Golubeva, D. S. Tsvetkov, M. M. Levitskii, and M. A. Kazankova, Carbon Tetrabromide-A New Brominating Agent for Alkanes and Arylalkanes, Russian Journal of Organic chemistry, 2002, V.38, № 7, p. 962
5. D. N. Kharitonov and E. N. Golubeva, Dimerization of Chlorocuprates in Weakly Polar Solvents, Kinetics and Сatalysis, 2003, 2003, т.44, №4, с.513.
6. D. N. Kharitonov and E. N. Golubeva, Mechanism of One-Electron Reactions of Copper(I) Chloride Complexes with Chlorohydrocarbons Kinetics and catalysis, 2005, V.46, №1, p. 52.
7. Zavyalov S.A., Schoonman J., Golubeva E.N., Lobanov A.V., Pivkina A.N., Gainutdinov R.V. The structure of thin film photoelectrode nanocomposites based on a matrix of poly-p-xylylene // Nanotechnologies in Russia. 2007. V. 2. № 3-4. P. 101-108.
8. E. N. Golubeva, G. M. Zhidomirov, and A. I. Kokorin, On the Stability of Copper(II) Organic Compounds with the Bond Cu–C: A Quantum-Chemical Study, Doklady Chemistry, 2009, V. 426, p. 143
9. Golubeva E.N., Lobanov A.V., Pergushov V.I., Chumakova N.A., Kokorin A.I. Copper(II) Organic compounds as intermediates of photochemical transformation of quaternary ammonium tetrachlorocuprates // Doclady Chemistry. V. 421. № 2. P. 171-174.
10. Formation of Active Catalysts in the System: Chlorocuprates-CCl4-n-C10H22. Elena N. Golubeva, Dmitry N. Kharitonov, Dmitry I. Kochubey, Vladimir N. Ikorskii, Vladimir V. Kriventsov, Alexander I. Kokorin, Julia Stoetsner, Detlef W. Bahnemann // The Journal of Physical Chemistry A 2009/ V.113 (38), 10219-10223
11. Lobanov A.V., Golubeva E.N., Zubanova E.M., Mel’nikov M.Ya. Photochemistry of tetraalkylammonium tetrachlorocuprates in low-temperature matrices // High Energy Chemistry. 2009. V. 43. № 5. P. 384-390.
12. Lobanov A.V., Golubeva E.N, Mel'nikov M.Ya. Photochemical synthesis and interconversions of organocopper(II) complexes in low-temperature matrices: an EPR study // Mendeleev Commun. 2010. V. 20. P. 343-345.

Scientific collaborations

• N.N. Semenov Institute of Chemical Physics RAS (Prof. A.I. Kokorin) Russia, Moscow http://www.chph.ras.ru
• Boreskov Institute of Catalysis SB RAS, Russia, Novosibirsk (Prof. D.I. Kochubei, V.V. Kriventsov) http://www.catalysis.ru
• Institute of Chemical Kinetics and Combustionof the Siberian Branch of RAS, Russia, Novosibirsk (Prof. V.F. Plyusnin) http://www.kinetics.nsc.ru
• Internatioal Tomography Center of the Siberian Branch of RAS, Russia, Novosibirsk (Prof. E.G. Bagryanskaya) http://www.tomo.nsc.ru
• Bergische Universitaet Wuppertal North Rhine-Westphalia, Germany (prof. R.J.Buenker) http://www.uni-wuppertal.de