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M. Ya. Melnikov, Ye. A. Belokon, V. N. Belevskii, A. D. Kalugina, O. L. Melnikova, V. I. Pergushov, M. P. Yegorov
Photochemical transformations of cyclic acetals
radical cations in freonic matrices at
77 K
Abstract
The efficiency of the
photochemical reactions of cyclic acetals radical cations (1,3-dioxolane,
1,3-dioxane) is measured in different freonic matrices at 77 K and also tHe
influence of matrix on the reaction path is discovered. The suggestions of
nature of paramagnetic complexes formed in photochemical reactions of cyclic
acetals in freon-11 are made.
Copyright (C) Chemistry Dept., Moscow State University, 2002
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